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CONTENTS
reface page vii
ist of constants, conversions, and prefixes xii
ar t I Setting the scene 1
1 Introduction 3
art II Small systems 23
2 Statistics for small systems 25
3 Systems with many elements 40
art III Energy and the first law 63
4 Internal energy 65
5 Interactions between systems 79
art IV States and the second law 99
6 Internal energy and the number of accessible states 101
7 Entropy and the second law 117
8 Entropy and thermal interactions 135
art V Constraints 153
9 Natural constraints 155
0 Models 186
1 Choice of variables 210
2 Special processes 226
3 Engines 252
4 Diffusive interactions 287
art VI Classical statistics 327
5 Probabilities and microscopic behaviors 329
6 Kinetic theory and transport processes in gases 352
7 Magnetic properties of materials 369
8 The partition function 382
Par t VII Quantum statistics 399
19 Introduction to quantum statistics 401
20 Quantum gases 422
21 Blackbody radiation 438
22 The thermal properties of solids 457
23 The electrical properties of materials 477
24 Low temperatures and degenerate systems 504
Appendices 531
Further reading 537
Problem solutions 538
Index 551
ist of constants, conversions, and prefixes xii
ar t I Setting the scene 1
1 Introduction 3
art II Small systems 23
2 Statistics for small systems 25
3 Systems with many elements 40
art III Energy and the first law 63
4 Internal energy 65
5 Interactions between systems 79
art IV States and the second law 99
6 Internal energy and the number of accessible states 101
7 Entropy and the second law 117
8 Entropy and thermal interactions 135
art V Constraints 153
9 Natural constraints 155
0 Models 186
1 Choice of variables 210
2 Special processes 226
3 Engines 252
4 Diffusive interactions 287
art VI Classical statistics 327
5 Probabilities and microscopic behaviors 329
6 Kinetic theory and transport processes in gases 352
7 Magnetic properties of materials 369
8 The partition function 382
Par t VII Quantum statistics 399
19 Introduction to quantum statistics 401
20 Quantum gases 422
21 Blackbody radiation 438
22 The thermal properties of solids 457
23 The electrical properties of materials 477
24 Low temperatures and degenerate systems 504
Appendices 531
Further reading 537
Problem solutions 538
Index 551
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